MAC How To Use VPN for only specific hosts or ip addresses

Hi, 

I would like to use my ISP for most of my traffic, since it's really fast. Then I would only like to use the VPN for specific hosts, or ip addresses. For example, www.bitstamp.net, is banned in my country. So I would like to use my ISP for all hosts, but except for when connecting to www.bitstamp.net, I'd like to route it to the VPN. 

Is this possible with Private Internet Access?

Please help. 

Thanks.
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