iOS app no longer connecting after enabling IPv6 in my home network

So I recently moved to a new ISP that supports IPv6 natively. I enabled it yesterday, and all the devices at home now have an IPv6 address as well. The PIA app on Windows still works correctly, and IPv6 leak protection is doing its job.

However. The PIA app on iOS is no longer connecting. It gets stuck at "Connecting..." and never completes. Any ideas why? Thanks in advance.
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